Arsenal last face Barcelona in the second of the Champions League in 2011. They won the first leg at the Emirate Stadium 2-1 before losing the second leg, 3-1.
In other fixtures, Gent will face Wolfsburg, Real Madrid will play Real Madrid while Paris Saint-Germain and Chelsea will meet the knockout stage of the Champions League in two consecutive seasons.
The Ligue 1 leaders knocked out the Premier League defending champions last season.
After slipping up on the last to a second in their group, Juventus will face Bayern Munich while PSV Eindhoven will play Atlético Madrid.
Benfica face Zenit while Dynamo Kyiv play Manchester City.
The group runners-up will play the first leg at home.
Fixtures:
Gent v Wolfsburg
Roma v Real Madrid
Paris v Chelsea
Arsenal v Barcelona
Juventus v Bayern
PSV v Atlético
Benfica v Zenit
Dynamo Kyiv v Man. City
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